• Laser & Optoelectronics Progress
  • Vol. 61, Issue 9, 0914008 (2024)
Jitai Han, Qingfeng Xia*, Keqing Wang, and Guoxiang Hua
Author Affiliations
  • School of Automation, Wuxi University, Wuxi 214105, Jiangsu, China
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    DOI: 10.3788/LOP231364 Cite this Article Set citation alerts
    Jitai Han, Qingfeng Xia, Keqing Wang, Guoxiang Hua. Microstructure Evolution and Properties of WC/Ni Based Coating on the Surface of 12CrMoV Alloy Steel by Laser Cladding[J]. Laser & Optoelectronics Progress, 2024, 61(9): 0914008 Copy Citation Text show less
    Single channel morphologies of different coating samples. (a) W10; (b) W20; (c) W30
    Fig. 1. Single channel morphologies of different coating samples. (a) W10; (b) W20; (c) W30
    XRD pattern of W20 coating
    Fig. 2. XRD pattern of W20 coating
    Microstructures of W20 coating
    Fig. 3. Microstructures of W20 coating
    Microstructures of WC/Ni based coatings. (a) (b) W10 coating; (c) (d) W20 coating; (e) (f) W30 coating
    Fig. 4. Microstructures of WC/Ni based coatings. (a) (b) W10 coating; (c) (d) W20 coating; (e) (f) W30 coating
    Mechanical properties of WC/Ni based coatings. (a) Microhardness; (b) COF; (c) average COF; (d) wear volume
    Fig. 5. Mechanical properties of WC/Ni based coatings. (a) Microhardness; (b) COF; (c) average COF; (d) wear volume
    Wear morphologies of WC/Ni based coatings. (a) W10 coating; (b) W20 coating; (c) W30 coating; (d) mapping of Fig.6(b)
    Fig. 6. Wear morphologies of WC/Ni based coatings. (a) W10 coating; (b) W20 coating; (c) W30 coating; (d) mapping of Fig.6(b)
    Polarization curves of WC/Ni based coatings
    Fig. 7. Polarization curves of WC/Ni based coatings
    Equivalent circuit
    Fig. 8. Equivalent circuit
    Nyquist and Bode plots of WC/Ni based coatings. (a) Nyquist plot; (b) Bode plot
    Fig. 9. Nyquist and Bode plots of WC/Ni based coatings. (a) Nyquist plot; (b) Bode plot
    MaterialAtomic fraction /%
    CBSiFeCrNiMoVPSCu
    12CrMoV0.08~0.150.17~0.37Bal.0.90~1.200.25~0.350.15~0.30≤0.35≤0.35≤0.25
    Ni600.70~1.103.00~4.003.50~5.00≤515.00~17.00Bal.
    Table 1. Chemical composition of Ni60 and 12CrMoV
    AreaAtomic fraction /%
    CFeCrNiSW
    A22.1716.3018.159.4633.92
    B9.0624.3222.8337.286.51
    C14.6930.8030.208.440.778.75
    Table 2. Element proportion of phase
    SampleAverage grain size
    Equiaxed grainColumnar grain
    W106.38(±0.41)11.32(±0.27)
    W204.35(±0.32)9.63(±0.25)
    W304.17(±0.12)9.21(±0.41)
    Table 3. Average grain size of W10,W20,W30
    SampleElectrochemical parameter
    Ecorr vs. SCE(saturated calomel electrode)/VIcorr /(10-5 A/cm2
    W10-0.74218.60
    W20-0.8783.65
    W30-0.7555.28
    Table 4. Electrochemical parameters obtained by Tafel empirical law and polarization curves
    SampleRs /(Ω·cm2Qf /(Ω-1·Sn·cm-2n1Rf /(Ω·cm2Qdl /(Ω-1·Sn·cm-2n2Rct /(Ω·cm2
    W104.5431.884×10-40.69026.1706.699×10-40.71206828
    W204.7223.625×10-40.660416.9309.648×10-50.88567782
    W304.9541.318×10-40.63887.0484.590×10-40.70037249
    Table 5. Equivalent circuit fitting results
    Jitai Han, Qingfeng Xia, Keqing Wang, Guoxiang Hua. Microstructure Evolution and Properties of WC/Ni Based Coating on the Surface of 12CrMoV Alloy Steel by Laser Cladding[J]. Laser & Optoelectronics Progress, 2024, 61(9): 0914008
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