• Spectroscopy and Spectral Analysis
  • Vol. 40, Issue 12, 3895 (2020)
Hao-yue JIA1、1、*, Gu-qing GUO1、1, Fu-qiang ZHAO1、1, Yong HU1、1, and Chuan-liang LI1、1
Author Affiliations
  • 1[in Chinese]
  • 11. School of Mechanical Engineering, Taiyuan University of Science and Technology, Taiyuan 030024, China
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    DOI: 10.3964/j.issn.1000-0593(2020)12-3895-06 Cite this Article
    Hao-yue JIA, Gu-qing GUO, Fu-qiang ZHAO, Yong HU, Chuan-liang LI. Investigation on Hardness of D2 Steel Based on Laser-Induced Breakdown Spectroscopy[J]. Spectroscopy and Spectral Analysis, 2020, 40(12): 3895 Copy Citation Text show less
    The microstructure of 6 samples for group 1(a): Martensite in as-cast; (b): Pearlite+ferrite; (c): Martensite in quenching; (d): Martensite in tempering; (e): Tempered troostite+tempering
    Fig. 1. The microstructure of 6 samples for group 1
    (a): Martensite in as-cast; (b): Pearlite+ferrite; (c): Martensite in quenching; (d): Martensite in tempering; (e): Tempered troostite+tempering
    The experimental setup of LIBS for the detection of D2 steel
    Fig. 2. The experimental setup of LIBS for the detection of D2 steel
    Typical LIBS spectrum of sample 1
    Fig. 3. Typical LIBS spectrum of sample 1
    Spectral line intensities of Fe, Mn element for 6 samples
    Fig. 4. Spectral line intensities of Fe, Mn element for 6 samples
    Spectral line intensities of Fe, Mn elements for 6 samples versus hardness
    Fig. 5. Spectral line intensities of Fe, Mn elements for 6 samples versus hardness
    Ferrum Ionic to atomic intensity ratio versus the surface hardness of D2 steel
    Fig. 6. Ferrum Ionic to atomic intensity ratio versus the surface hardness of D2 steel
    Boltzmann plots of the studied samples
    Fig. 7. Boltzmann plots of the studied samples
    Plasma excitation temperatures versus sample hardness
    Fig. 8. Plasma excitation temperatures versus sample hardness
    The hardness and LIBS spectrum versus different increment of manganese samples
    Fig. 9. The hardness and LIBS spectrum versus different increment of manganese samples
    ElementMass fraction/%ElementMass fraction/%
    C1.59Si1.00
    S0.015Cr11.68
    P0.02Mo0.71
    Mn0.65
    Table 1. Main chemical compositions of D2 steel(wt. %)
    NumberThermal
    treatment
    MicrostructureRockwell
    hardness
    (HRC)
    1raw materialLath martensite51
    2850 ℃ annealingPearlite+ferrite20
    3850 ℃ quenchingLath martensite59.9
    4200 ℃ temperingMartensite58.3
    5500 ℃ temperingTroostite40.8
    6600 ℃ temperingTroostite+Sorbite35.5
    Table 2. Microstructure and hardness of experimental samples for group 1(HRC)
    SampleThe added
    content
    of Mn/%
    The content
    of Mn
    /g
    Rockwell
    hardness
    (HRC)
    1#-0.1351
    2#0.500.229 452.5
    3#10.328 761.7
    4#1.500.428 163.6
    5#20.527 462.2
    Table 3. Five samples with different content of manganese and their hardness respectivelyzz
    Wavelength/nmLower level
    Ei/eV
    Upper level
    Ek/eV
    Transition probability
    Aki/(108 s-1)
    Statistical
    weight gk
    Fe Ⅰ 373.480.858 995 754.177 696 750.90111
    Fe Ⅰ 401.453.046 868 886.134 381 880.1537
    Fe Ⅰ 402.192.758 577 605.840 459 610.085 59
    Fe Ⅰ 404.581.484 864 384.548 506 090.8629
    Fe Ⅱ 275.570.986 333 795.484 135 952.1510
    Mn Ⅰ 403.070.03.075 0870.178
    Table 4. Atomic and ionic spectral lines of the analyzed elements
    Hao-yue JIA, Gu-qing GUO, Fu-qiang ZHAO, Yong HU, Chuan-liang LI. Investigation on Hardness of D2 Steel Based on Laser-Induced Breakdown Spectroscopy[J]. Spectroscopy and Spectral Analysis, 2020, 40(12): 3895
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