• Journal of Inorganic Materials
  • Vol. 37, Issue 7, 773 (2022)
Shun ZOU1、2, Xiyun HE1、*, Xia ZENG1, Pingsun QIU1, Liang LING1, and Dazhi SUN2、*
Author Affiliations
  • 11. Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
  • 22. College of Chemistry and Materials Science, Shanghai Normal University, Shanghai 200234, China
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    DOI: 10.15541/jim20210603 Cite this Article
    Shun ZOU, Xiyun HE, Xia ZENG, Pingsun QIU, Liang LING, Dazhi SUN. Microstructure and Properties of Bi-doped Yttrium Iron Garnet Magneto-optical Ceramics Prepared by Hot-pressing Sintering Process[J]. Journal of Inorganic Materials, 2022, 37(7): 773 Copy Citation Text show less
    Density of BixY1-xFe5O12 ceramic samples varies with sintering temperatures (a) and photos of BixY1-xFe5O12 samples (b)
    1. Density of BixY1-xFe5O12 ceramic samples varies with sintering temperatures (a) and photos of BixY1-xFe5O12 samples (b)
    Infrared transmittance curves of BixY1-xFe5O12 samples sintered at different temperatures (d=0.4 mm)
    2. Infrared transmittance curves of BixY1-xFe5O12 samples sintered at different temperatures (d=0.4 mm)
    Best infrared transmittance curves of BixY1-xFe5O12 samples with Bi3+ doping (d=0.4 mm)
    3. Best infrared transmittance curves of BixY1-xFe5O12 samples with Bi3+ doping (d=0.4 mm)
    XRD patterns of BixY1-xFe5O12 (x=0, 0.3, 0.6, 0.9) samples (a) and the detail map at 2θ=68°-70° (b)
    4. XRD patterns of BixY1-xFe5O12 (x=0, 0.3, 0.6, 0.9) samples (a) and the detail map at 2θ=68°-70° (b)
    Cross-section SEM images of the BixY1-xFe5O12 ceramic samples
    5. Cross-section SEM images of the BixY1-xFe5O12 ceramic samples
    SEM image (a) and EDS patterns of the Bi0.9Y2.1Fe5O12 ceramics sintered at 1050 ℃ (b, c)
    6. SEM image (a) and EDS patterns of the Bi0.9Y2.1Fe5O12 ceramics sintered at 1050 ℃ (b, c)
    Schematic diagram of Faraday rotation angle test equipment (a), hysteresis loops (b) of BixY1-xFe5O12 samples, and Faraday rotation angle of the ceramic sample varies with the proportion of bismuth at 1064 and 1550 nm (c)
    7. Schematic diagram of Faraday rotation angle test equipment (a), hysteresis loops (b) of BixY1-xFe5O12 samples, and Faraday rotation angle of the ceramic sample varies with the proportion of bismuth at 1064 and 1550 nm (c)
    BixY1-xFe5O12Sintering temperature of the sample with the highest density/℃ Sintering temperature of the sample with the highest transmittance/℃
    x=0 13001300
    x=0.3 12501250
    x=0.6 12501150
    x=0.9 11501050
    Table 1. Sintering temperatures of the samples with the highest density and the highest transmittance
    xResidual magnetization, 4πMr /T Saturation magnetization, 4πMs /T Coercive field, Hc / (A·m-1)
    01.32×10-20.15436029.6
    0.36.59×10-30.1577369.2
    0.65.02×10-40.1596310.4
    0.92.86×10-40.1536179.8
    Table 2. Magnetic performance parameters of the sintered BixY1-xFe5O12 samples with different amounts of Bi3+doping
    Shun ZOU, Xiyun HE, Xia ZENG, Pingsun QIU, Liang LING, Dazhi SUN. Microstructure and Properties of Bi-doped Yttrium Iron Garnet Magneto-optical Ceramics Prepared by Hot-pressing Sintering Process[J]. Journal of Inorganic Materials, 2022, 37(7): 773
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