• Journal of Inorganic Materials
  • Vol. 38, Issue 8, 885 (2023)
Junsheng LI, Liang ZENG, Rongjun LIU, Yanfei WANG, Fan WAN, and Duan LI*
Author Affiliations
  • Science and Technology on Advanced Ceramic Fibers and Composites Laboratory, College of Aerospace Science and Engineering, National University of Defense Technology, Changsha 410073, China
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    DOI: 10.15541/jim20230026 Cite this Article
    Junsheng LI, Liang ZENG, Rongjun LIU, Yanfei WANG, Fan WAN, Duan LI. Functional Strontium Tantalum Oxynitride Ceramics: Efficient Synthesis, Densification and Dielectric Performance[J]. Journal of Inorganic Materials, 2023, 38(8): 885 Copy Citation Text show less
    Preparation flow chart of the SrTa(O,N)3 ceramic bulk
    1. Preparation flow chart of the SrTa(O,N)3 ceramic bulk
    XRD patterns (a) and Raman spectra (b) of the products obtained at different heating rates
    2. XRD patterns (a) and Raman spectra (b) of the products obtained at different heating rates
    Optical and SEM images of the products obtained at different heating rates
    3. Optical and SEM images of the products obtained at different heating rates
    XRD patterns (a) and Raman spectra (b) of the products obtained at different synthesis temperatures
    4. XRD patterns (a) and Raman spectra (b) of the products obtained at different synthesis temperatures
    Optical and SEM images of the products obtained at different synthesis temperatures
    5. Optical and SEM images of the products obtained at different synthesis temperatures
    Rietveld refinement of XRD pattern for SrTa(O,N)3
    6. Rietveld refinement of XRD pattern for SrTa(O,N)3
    SEM image and EDS mappings of SrTa(O,N)3 powder prepared under optimized conditions
    7. SEM image and EDS mappings of SrTa(O,N)3 powder prepared under optimized conditions
    XRD patterns of SrTa(O,N)3 bulk obtained by SPS
    8. XRD patterns of SrTa(O,N)3 bulk obtained by SPS
    SEM and optical images of SrTa(O,N)3 bulk obtained by SPS process
    9. SEM and optical images of SrTa(O,N)3 bulk obtained by SPS process
    Dielectric performance curves of SrTa(O,N)3 ceramic bulk (300 Hz-1 MHz)
    10. Dielectric performance curves of SrTa(O,N)3 ceramic bulk (300 Hz-1 MHz)
    Dielectric constants at low frequency ranges of SrTa(O,N)3 ceramic bulk in this work and literatures[11-12,14,24]
    11. Dielectric constants at low frequency ranges of SrTa(O,N)3 ceramic bulk in this work and literatures[11-12,14,24]
    SampleSynthesis temperature /℃Heating rate /(℃·min-1) Composition/% (in atomic)O/N
    SrTaON
    STON-1000-101000109.1911.0561.5118.253.37
    STON-800-10080010014.597.7457.1020.572.78
    STON-900-10090010012.6010.9850.2426.181.92
    STON-1000-100100010011.7411.9247.8328.511.68
    STON-1100-100110010010.6313.0244.8631.491.42
    STON-1200-100120010010.1113.5044.1732.221.37
    Table 1. Synthesis conditions (heating strategy) and element content
    SampleHeating rate/(℃·min-1) Sintering temperature/℃ Dwell time/min Density/(g·cm-3) Relative density/% Open porosity/% (Open porosity/ Total porosity)/%
    STON-SPS-1300110015.6970.943.1210.77
    STON-SPS-2300120016.3078.547.5435.28
    STON-SPS-3300125006.9386.404.3721.90
    STON-SPS-4300125017.1388.890.433.89
    STON-SPS-5300125037.2490.260.575.88
    STON-SPS-6200130017.3791.880.698.53
    STON-SPS-7300130017.5594.130.559.52
    STON-SPS-8300140017.6795.620.4911.53
    Table 2. Density and porosity of oxynitride ceramics prepared by different SPS processes (100 MPa)
    Junsheng LI, Liang ZENG, Rongjun LIU, Yanfei WANG, Fan WAN, Duan LI. Functional Strontium Tantalum Oxynitride Ceramics: Efficient Synthesis, Densification and Dielectric Performance[J]. Journal of Inorganic Materials, 2023, 38(8): 885
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