This paper experimentally demonstrates a distributed photonics-based W-band integrated sensing and communication (ISAC) system, in which radar sensing can aid the communication links in alignment and data rate estimation. As a proof-of-concept, the ISAC system locates the users, guides the alignment, and sets a communication link with the estimated highest data rate. A peak net data rate of 68.6 Gbit/s and a target sensing with a less-than-1-cm error and a sub-2-cm resolution have been tested over a 10-km fiber and a 1.15-m free space transmission in the photonics-based W-band ISAC system. The achievable net data rates of the users at different locations estimated by sensing are experimentally verified.