• Chinese Journal of Chemical Physics
  • Vol. 33, Issue 5, 649 (2020)
Fang-fang Li, Yu-jie Ma, Jia-xing Liu, Guan-jun Wang, and Feng-yan Wang*
DOI: 10.1063/1674-0068/cjcp2007118 Cite this Article
Fang-fang Li, Yu-jie Ma, Jia-xing Liu, Guan-jun Wang, Feng-yan Wang. Photodissociation Dynamics of AlO at 193 nm using Time-Sliced Ion Velocity Imaging[J]. Chinese Journal of Chemical Physics, 2020, 33(5): 649 Copy Citation Text show less

Abstract

The photodissociation dynamics of AlO at 193 nm is studied using time-sliced ion velocity mapping. Two dissociation channels are found through the speed and angular distributions of aluminum ions: one is one-photon dissociation of the neutral AlO to generate Al($ ^2 $P$ _ \rm{u} $)+O($ ^3 $P$ _ \rm{g} $), and the other is two-photon ionization and then dissociation of AlO$ ^+ $ to generate Al$ ^+ $($ ^1 $S$ _ \rm{g} $)+O($ ^3 $P$ _ \rm{g} $). Each dissociation channel includes the contribution of AlO in the vibrational states $ v $ = 0-2. The anisotropy parameter of the neutral dissociation channel is more dependent on the vibration state of AlO than the ion dissociation channel.
Fang-fang Li, Yu-jie Ma, Jia-xing Liu, Guan-jun Wang, Feng-yan Wang. Photodissociation Dynamics of AlO at 193 nm using Time-Sliced Ion Velocity Imaging[J]. Chinese Journal of Chemical Physics, 2020, 33(5): 649
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