• Journal of Semiconductors
  • Vol. 40, Issue 8, 081510 (2019)
Na Chen1, Kaixuan Fang1, Hongxia Zhang1, Yingqi Zhang1, Wenjian Liu1, Kefu Yao1, and Zhengjun Zhang2
Author Affiliations
  • 1Key Laboratory for Advanced Materials Processing Technology (MOE), School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China
  • 2Key Laboratory for Advanced Materials (MOE), School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China
  • show less
    DOI: 10.1088/1674-4926/40/8/081510 Cite this Article
    Na Chen, Kaixuan Fang, Hongxia Zhang, Yingqi Zhang, Wenjian Liu, Kefu Yao, Zhengjun Zhang. Amorphous magnetic semiconductors with Curie temperatures above room temperature[J]. Journal of Semiconductors, 2019, 40(8): 081510 Copy Citation Text show less

    Abstract

    Recently, amorphous magnetic semiconductors as a new family of magnetic semiconductors have been developed by oxidizing ferromagnetic amorphous metals/alloys. Intriguingly, tuning the relative atomic ratios of Co and Fe in a Co-Fe-Ta-B-O system leads to the formation of an intrinsic magnetic semiconductor. Starting from high Curie-temperature amorphous ferromagnets, these amorphous magnetic semiconductors show Curie temperatures well above room temperature. Among them, one typical example is a p-type Co28.6Fe12.4Ta4.3B8.7O46 magnetic semiconductor, which has an optical bandgap of ~2.4 eV, room-temperature saturation magnetization of ~433 emu/cm3, and the Curie temperature above 600 K. The amorphous Co28.6Fe12.4Ta4.3B8.7O46 magnetic semiconductor can be integrated with n-type Si to form p–n heterojunctions with a threshold voltage of ~1.6 V, validating its p-type semiconducting character. Furthermore, the demonstration of electric field control of its room-temperature ferromagnetism reflects the interplay between the electricity and ferromagnetism in this material. It is suggested that the carrier density, ferromagnetism and conduction type of an intrinsic magnetic semiconductor are controllable by means of an electric field effect. These findings may pave a new way to realize magnetic semiconductor-based spintronic devices that work at room temperature.
    $ {V_{\rm{D}}} = \frac{1}{q}\left( {{E_{{\rm{i2}}}} - {E_{{\rm{i1}}}} + kT\ln \frac{{{N_{\rm{A}}}{N_{\rm{D}}}}}{{{n_{{\rm{i1}}}}{n_{{\rm{i2}}}}}}} \right). $ (1)

    View in Article

    Na Chen, Kaixuan Fang, Hongxia Zhang, Yingqi Zhang, Wenjian Liu, Kefu Yao, Zhengjun Zhang. Amorphous magnetic semiconductors with Curie temperatures above room temperature[J]. Journal of Semiconductors, 2019, 40(8): 081510
    Download Citation