• Acta Photonica Sinica
  • Vol. 51, Issue 1, 0151124 (2022)
Xiaowei JIANG1、3, Sheng WANG1、*, and Hua WU2、3
Author Affiliations
  • 1College of Information Engineering,Quzhou College of Technology,Quzhou,Zhejiang 324000,China
  • 2College of Physics and Electronic Information,GanNan Normal University,Ganzhou,Jiangxi 341000,China
  • 3Key Laboratory of Opto-electronics Technology Ministry of Education,Beijing University of Technology,Beijing 100124,China
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    DOI: 10.3788/gzxb20225101.0151124 Cite this Article
    Xiaowei JIANG, Sheng WANG, Hua WU. Metamaterial Absorber with Tunable Absorption Bandwidth Based on Vanadium Dioxide[J]. Acta Photonica Sinica, 2022, 51(1): 0151124 Copy Citation Text show less

    Abstract

    Metamaterial Perfect Absorber (MPA) is currently a research hotspot because of its numerous advantages such as high absorption efficiency, ultra-thin thickness, simple structure and so on. Since Landy et al. first proposed an MPA with perfect absorption characteristics, different types of MPAs have been proposed, and the absorption wavelengths over microwave, terahertz, infrared, and visible bands have been identified. However, once the structural parameters of MPA are fixed, the absorption bandwidth of MPA almost cannot be dynamically adjusted, which will limit its applications in some particular fields. This paper proposes a bandwidth-tunable MPA which is composed of vanadium dioxide (VO2) and Au. The research group simulated and analyzed the MPA based on Finite Difference Time Domain (FDTD) method. In the simulation, a periodic boundary condition was added in x- and y-directions, and a perfect match layer was added in the z-direction as the boundary condition. The polarization of the incident light was set to be TM polarization (Along the x axis). Incident light was perpendicular to the surface of the structure, which indicated the incident angle θ is 0. The simulation results show that the tuning range of absorption bandwidth can achieve 0.378 μm by controlling the temperature of VO2, and the absorption wavelength of MPA covered visible and near-infrared light. To explore the physical explanation for the high absorption efficiency in different wavelengths, we analyzed electromagnetic field distribution in MPA in different wavelengths, and revealed that although the high absorption efficiency is caused by the incident-light-stimulated surface plasmons in MPA, the working mechanism in visible and near infrared wavelength is quite different. In visible light range, no matter vanadium dioxide is in metallic state or dielectric state, the high absorption efficiency is caused by Propagating Surface Plasmon (PSP). On the other hand, for near-infrared light, if vanadium dioxide is in dielectric state, the high absorption efficiency is due to the Localized Surface Plasmon (LSP); or if vanadium dioxide is in metallic state, the high absorption efficiency is due to Fabry-Perot (FP) cavity resonance. Our results show that the MPA has the potential to be used in applications such as optical integrated devices and thermal emitters.

    0 Introduction

    Adjusting the Metamaterial(MM)cell resonance structure may show many exotic electromagnetic properties,such as negative refraction1-2,perfect absorption3-4,electromagnetic stealth5-6,and electromagnetic induction transparency7. Because MM has the above-mentioned abnormal electromagnetic properties,it has gradually become a research hotspot,and has been widely used in national defense,communications,and biomedical sensing.[8-10.

    The Metamaterial Perfect Absorber(MPA)has attracted widespread attention due to unprecedented characteristics compared to taper-like structure absorbers11 or ordinary absorbers,such as high absorption efficiency,ultrathin thickness,and a scalable working wavelength12. Since Landy et al. first proposed an MPA with perfect absorption characteristics3,different types of MPAs have been proposed,and the absorption wavelengths over microwave13,terahertz14,infrared,15 and visible bands have been identified16. However,once the structural parameters of MPAs are fixed,their absorption characteristics are difficult to be tuned. On the other hand,demand on tunable MPA is increasing in many applications,such as modulators,optical switches,and smart reflectors.17.

    To realize the dynamic tunability of the absorption characteristics of MPA,many research groups choose to incorporate varactor diodes or graphene into the design of MPA. In the low-frequency band,diodes with changeable capacitance are generally used to change the equivalent capacitance of MPA to achieve dynamic tuning of MPA absorption wavelength and absorption efficiency18-19. In the high-frequency band,graphene is used in MPA. By changing the chemical potential of graphene,one can achieve dynamic control of absorption wavelength,absorption efficiency,and even absorption bandwidth of MPAs20-21.

    In recent years,phase-changing material vanadium dioxide(VO2)demonstrated outstanding optical and electrical properties,and can realize the transition between metallic state and dielectric state through external excitations,such as light,electricity,and heat22-23. Because VO2 has reversible phase-changing characteristics,it is an ideal material for preparing a tunable MPA,and many research work has been done on tunable MPAs based on VO2. LEI L et al from Shenzhen University designed an absorption-bandwidth-tunable MPA based on VO2 and metallic chromium materials24. DAO Rina et al from Nanjing University of Posts and Telecommunications used VO2 as a resonance unit material,and the absorption efficiency of MPA could be tuned by changing the temperature of the resonance unit 25. Our research group also demonstrated tunable absorption wavelength and absorption efficiency of MPA by using VO2 and graphene in MPA26.

    To the best of our knowledge,current VO2-based MPA can realize tunable absorption efficiency,but the tuning of absorption bandwidth is rarely involved. Moreover,the tunable MPA bandwidth in visible and near-infrared bands is even less involved. However,at present,for the application of intelligent windows,intelligent reflectors,intelligent temperature control systems,and heat emitters,MPA absorption bandwidth is required to be tunable in the visible and near-infrared bands27-28. Therefore,in this paper,a bandwidth-tunable VO2-based MPA in visible and near-infrared bands is proposed and studied using Finite Difference Time Domain(FDTD)method. The simulation results showed that the bandwidth,Wa, of the tunable MPA proposed in this paper could reach 1.03 μm and 0.652 μm with absorption efficiency higher than 90% in the VO2 dielectric and metallic state. By analyzing the electromagnetic field distribution of MPA,it was observed that as VO2 was in the dielectric state,MPA achieved a wide bandwidth and high absorption owing to the Propagating Surface Plasmon(PSP),Localized Surface Plasmon(LSP),and the resonance of Fabry-Perot(FP)cavity.

    1 Device structure and theory

    The structure of the absorption-bandwidth-tunable MPA is shown in Fig. 1. Fig. 1(a)is overall view of the MPA structure,and Fig. 1(b)is zoom-in view of one MPA unit cell. The MPA unit cell is composed of an Au substrate and four cylindrical resonance units with different radii. The cylindrical resonance units are of two-layered structure,with VO2 as bottom layer and Au as top layer. The structural parameters are as follows:P is the period of the MPA unit cell;r1r2r3, and r4 are the radii of the four cylindrical resonance units respectively;hm=0.03 μm and hv=0.11 μm are the thickness of Au and VO2 in the cylindrical resonance unit respectively;w1w2w3 and w4 are spacing between different cylinder resonant elements. In this work,the thickness of the Au substrate is 0.2 μm,which is thick enough to block the incident light effectively,and the transmission of the structure is nearly zero.

    schematic of the structure of absorption-bandwidth-tunable MPA

    Figure 1.schematic of the structure of absorption-bandwidth-tunable MPA

    With the development of material preparation technology and nanofabrication technology,the current micro-nano machining technology can fully meet the requirements of MPA processing as shown in Fig. 1. Therefore,the MPA structure proposed in this paper is easier to realize in an actual experiment. The proposed structure in Fig. 1 can easily be realized by current nano-fabrication technology. Firstly,a continuous VO2 layer is prepared on the Au substrate by the lower-cost sol-gel method 29,then a thin Au layer was sputtered on the VO2 layer by magnetron sputtering,finally the required cylindrical resonance units are patterned by electron beam lithography and ion beam etching.

    The refractive index n,and coefficient k of Au for different light wavelengths could be obtained from Ref.[30],as shown in Fig. 2. According to the Bruggeman's effective medium theory31,The dielectric constant of VO2 could be calculated by Eq.(1). In Eq.(1)εi≈9 is the dielectric constant of VO2 in the dielectric state,εm is the dielectric constant of VO2 in the metallic state,and f represents the volume ratio of VO2 in the metallic state in the entire VO2. Moreover,εm could be obtained by Eq.(2). In Eq.(2)ωp is the plasma frequency,ω is the incident light angular frequency,τ=2 μme/e is the relaxation time,me is the mass of free electrons,u≈2 cm2/V. s is carrier mobility,and e is the amount of free electron charge. Furthermore,f could be obtained by Eq.(3),where T represents the environment temperature,T0=68°C represents the VO2 phase transition temperature,and ΔT=6°C is the transition width. Eqs.(1)~(3)could be combined to obtain the refractive index,nVO2 and the extinction coefficient,kVO2 of VO2 for different wavelengths at different temperatures,as shown in Fig. 3.

    εVO2=14{εi(2-3f)+εm(3f-1)+[εi(2-3f)+εm(3f-1)]2+8εiεm}
    εm(ω)=εi+iωp2ω(ω+i/τ)
    f=1-11+exp[(T-T0)/ΔT]

    Refractive index and extinction coefficient of Au

    Figure 2.Refractive index and extinction coefficient of Au

    Refractive index and extinction coefficient of VO2 at different temperatures

    Figure 3.Refractive index and extinction coefficient of VO2 at different temperatures

    2 Results and discussions

    The characteristics of proposed MPA is studied by FDTD simulation. Since the MPA is of periodic structure,by carefully setting boundary conditions,it is feasible to only simulate the unit structure as shown in Fig. 1(b)in FDTD software. A periodic boundary condition was added in the x- and y-directions. A perfect match layer was added in the z-direction as the boundary condition. The polarization of the incident light was set to be TM polarization(Along the x axis). Incident light was perpendicular to the surface of the structure,which indicated the incident angle θ is 0. To ensure that the simulation results were closer to reality,the grid type was auto non-uniform during simulation,and the grid accuracy was set to the maximum value of 8. The details are shown in Fig. 4.

    Detailed settings of the FDTD simulation

    Figure 4.Detailed settings of the FDTD simulation

    Fig. 5 shows FDTD simulation results of absorption spectra of MPA at different temperatures. As Fig. 5 shows,at T=80°C,the MPA could maintain more than 90% absorption efficiency between 0.505 μm and 1.157 μm,and the absorption bandwidth Wa could reach 0.652 μm. When the temperature T dropped from 80°C to 25°C,the MPA could maintain more than 90% absorption efficiency between 0.505 μm and 1.535 μm,and the absorption bandwidth,Wa reached 1.03 μm. These findings indicate that the MPA proposed in this paper can realize the tuning of absorption bandwidth by changing the VO2 temperature,and the tuning range of absorption bandwidth can reach 0.378 μm. In addition,the results show that the absorption spectrum of MPA covers both the visible and near-infrared bands.

    Absorption as a function of wavelength of MPA at different temperature

    Figure 5.Absorption as a function of wavelength of MPA at different temperature

    To explore the internal physical mechanism of the MPA with tunable absorption bandwidth,the electromagnetic field distribution of MPA at different resonance wavelengths is simulated and calculated at low temperature. Fig. 6 shows the electric field distribution of MPA in the x-z plane(y=-0.125 μm,e.g. the center plane of cylinders with radii r3 and r4)under different resonance wavelength conditions(T=25°C). As shown in Fig. 6,under different resonance wavelength conditions,the electric field is basically concentrated between the gaps of the cylindrical resonance units and the corners of the Au cylinder,which indicates the incident light excites the surface plasmon polaritons(SPPs)in the MPA. Therefore,from the electric field distribution,it can be concluded that the high absorption of the MPA at each resonance wavelength is due to SPP resonance24.

    Electric field distribution of MPA at the different resonance wavelength(T=25°C)

    Figure 6.Electric field distribution of MPA at the different resonance wavelength(T=25°C)

    Unlike the electric field distribution,the magnetic field distribution(T=25°C)of the MPA under different resonance wavelength conditions is very different. As shown in Fig. 7(a)and 7(b),LSP resonance is the mainreason for the high absorption efficiency of MPA at long wavelengths(1.4 μm and 1.2 μm). Moreover,most of the magnetic field is confined to the VO2 layer,which is between the Au cylinder and the Au substrate23. Fig. 7(e)shows that the high absorption efficiency of MPA at a short wavelength(0.505 μm)is mainly due to PSP resonance,because only a small part of the magnetic field is restricted to the VO2 layer,and most of magnetic field is located between adjacent cylindrical resonance units,which is a significant PSP resonance feature32-33. The specific proof can also be seen in Fig. 9(a). As for the resonance absorption of MPA at wavelengths of 0.8 μm and 1 μm,Fig. 7(c) and 7(d) show that it is not only caused by LSP resonance and PSP resonance,but is also mixed with FP cavity resonance,that is,the light wave oscillated back and forth between the Au cylindrical layer and the Au substrate. In this case,the Au cylindrical layer and Au substrate act as mirrors to form a FP resonator.

    The magnetic field distribution of MPA at the different resonance wavelength(T=25°C)

    Figure 7.The magnetic field distribution of MPA at the different resonance wavelength(T=25°C)

    The electromagnetic field distribution of MPA at resonance wavelength(T=80°C)

    Figure 8.The electromagnetic field distribution of MPA at resonance wavelength(T=80°C)

    The influence of MPA structural parameters on the absorption spectrum of MPA(T=25°C)

    Figure 9.The influence of MPA structural parameters on the absorption spectrum of MPA(T=25°C)

    To understand the intrinsic physical mechanism of the high absorptivity of MPA in the VO2 metallic state,the electromagnetic field distribution of MPA at the wavelength of 0.505 μm and 1 μm at T=80°C is calculated,as shown in Fig. 8. Fig. 8(a)shows the magnetic field distribution of the MPA at a wavelength of 0.505 μm. Compared with Fig. 7(e),the magnetic field distribution of VO2 at the short wavelength is basically the same regardless of whether VO2 is in the dielectric state or metallic state. That is,the physical mechanism leading to the high absorption efficiency of MPA at the short wavelength is the same,which is because of the PSP resonance.

    Comparing Fig. 8(b)with Fig. 7(c),it can be seen that when VO2 is in the metallic state,the high absorption efficiency of MPA at long wavelengths(1 μm)is not only caused by LSP or PSP resonance,but also mainly because of FP cavity resonance. The FP cavity resonance here is mainly composed of an adjacent cylinder resonance units and air gap 24. The FP cavity length is the thickness of cylinder resonance unit(hm+hv). The width of FP cavity is w1. Owing to the formation of the FP cavity,more magnetic fields are concentrated between the air gaps of the adjacent cylinder resonance units. Figs. 8(c) and 8(d) show the electric field distribution of MPA at a wavelength of 0.505 μm and 1 μm when VO2 is in a metallic state,respectively. It can be seen the high absorption efficiency of MPA at high temperature is also due to the SPP resonance.

    To explore the influence of MPA structural parameters on its absorption characteristics at low temperature(VO2 is in dielectric state,T=25℃),the MPA absorption spectra(T=25°C)under the conditions of different periods P and cylindrical resonance unit radius were simulated and calculated. Fig. 9(a)shows the influence of P on the absorption spectrum of MPA. As P increased,the absorption bandwidth of MPA gradually narrowed,and the absorption wavelength of MPA at the short-wavelength gradually showed redshift. When P increased from 0.5 μm to 0.6 μm,the initial wavelength of the MPA absorption spectrum shifted from 0.505 μm to 0.599 μm. It can be found that the absorption wavelength of MPA at short wavelengths is very close to P. This phenomenon is due to the fact that high absorption efficiency of MPA at short wavelengths is caused by PSP resonance. The PSP resonance wavelength,λPSP is related to the MPA period, P,which can be seen in Eq.(4)32. In Eq.(4)m is an integer,λ0is the free-space wavelength. Because the incident light is perpendicular to the surface of the MPA,θ is 0,therefore λPSPequals to P.

    As Fig. 9(a)shows,although the P of MPA gradually increased,there is no obvious redshift or blueshift at the MPA wavelength of 1.4 μm. This is because,as can be seen from Fig. 7(a),the high absorption efficiency of MPA at 1.4 μm is caused by LSP resonance,and period P has almost no effect on the LSP resonance wavelength.

    1λPSP=1λ0sinθ+mP

    Fig. 9(b)shows the MPA absorption spectra versus the radii of different cylindrical resonance units. As can be seen from Fig. 9(b),with an increase in the radius of the resonance unit,the MPA absorption bandwidth,Wa, increased firstly and then decreased. In the short wavelength range between 0.5 μm and 1 μm,in all the 4 simulated conditions,the MPA could maintain a relatively high absorption efficiency(>75%). The reason for this is that the high absorption efficiency of MPA at short wavelength is caused by the PSP resonance,as shown in Fig. 7(e). From Eq.(4),we know the resonance wavelength of PSP is mainly determined by the period P,so as long as P did not change,the MPA could maintain the PSP resonance at the short wavelength. However,the absorption efficiency varied greatly at long wavelengths(>1 μm). The reason for this is that the high absorption efficiency of MPA at long wavelength is caused by LSP resonance,as shown in Fig. 7(a) and 7(b). According to Ref.[32],LSP resonance is mainly affected by the shape and size of the MPA resonance unit. Therefore,when the radius of the resonance unit is small,the absorption efficiency of MPA is extremely low because it cannot meet the conditions to excite LSP resonance;when the radius of the resonance element increases,it gradually meets the excitation conditions of LSP resonance,and increases the absorption efficiency of MPA at the long-wavelength range.

    In order to understand the influence of structural parameters on the absorption characteristics of MPA at high temperature(VO2 is in metallic state,T=80℃),we changed the thickness of top Au layer hm and the radius of the resonance units. Fig. 10(a)shows the influence of hm on the absorption characteristics of MPA as VO2 is in metallic state(T=80℃). As can be seen from Fig. 10(a),when hm increases,the absorption wavelength of MPA at short wavelength almost unchanged,but the absorption efficiency gradually declines. Refer to Fig. 8(a),when VO2 is in metallic state,the high absorption efficiency of MPA at the short wavelength is caused by the PSP resonance. On the contrary,the absorption wavelength of MPA in the long wavelength is red-shifted. This is because when VO2 is the metallic state(T=80℃),the high absorption efficiency of MPA at the long wavelength is due to the FP cavity resonance rather than LSP resonance. The relationship between the FP cavity resonance wavelength λFP and hm is shown in Eq.(5)34,where neff is the FP cavity effective refractive index. According to Eq.(5),with the increase of hm,the resonant wavelength of FP cavity λFP will increase,resulting in the red shift of MPA at the long wavelength.

    The influence of MPA structural parameters on the absorption spectrum of MPA(T=80°C)

    Figure 10.The influence of MPA structural parameters on the absorption spectrum of MPA(T=80°C)

    λFP=2(hv+hm)neff

    Fig. 10(b)shows the influence of the MPA resonance unit radius on the absorption characteristics of the MPA. Different from VO2 in dielectric state,when VO2 is in metallic state,the absorption efficiency of MPA at long wavelength gradually increases with the increase of the resonance unit radius. As comparison,when VO2 is in dielectric state,as shown in Fig. 9(b),with the increase of the resonance unit radius,the absorption efficiency of MPA at long wavelength first increases and then decreases. This is mainly because when VO2 is metallic state,the high absorption efficiency of MPA at long wavelength is due to the FP cavity resonance. With the increase of resonance unit radius,the FP equivalent refractive index gradually meets the resonance condition of long wavelength(see Fig. 11),so that the absorption efficiency of MPA at long wavelength is gradually improved.

    The influence of FP cavity wdith w on the FP cavity equivalent refractive index neff

    Figure 11.The influence of FP cavity wdith w on the FP cavity equivalent refractive index neff

    The relationship between the width of FP cavity w and the equivalent refractive index of FP cavity neff can be obtained by Eqs.(6)~(8). εm and εd=1 are the dielectric constants of Au and air respectively. k0=2π/λ,where λ is the incident light wavelength. Fig. 11 shows the relationship between w and neff when the wavelength of incident light is 1 μm(εm=-47.84+3.11i). It can be seen from Fig. 11 that as w decreases,that is,as the radius of the cylinder resonance unit increases,neff will gradually increase. Because the length of the FP cavity unchanged,the resonance wavelength λFP of the FP cavity will increase when the neff increases. Therefore,as shown in Fig. 10(b),when the radius of the cylindrical resonance unit increases,the absorption efficiency of MPA at the long wavelength increases.

    kdεmtanhkdw2+kmεd=0
    kd=k0neff2-εd
    km=k0neff2-εm

    3 Conclusions

    We designed a MPA with high absorption efficiency and tunable absorption bandwidth in visible and near-infrared light bands. The simulation results indicate that by changing temperature,the absorption bandwidth Wa of the MPA can be tuned,and the tuning range can reach 0.375 μm. We also studied the effects of structural parameters on absorption bandwidth. By analyzing the electromagnetic field of the MPA at absorption wavelength,it can be found that when VO2 is at a low temperature(T=25°C),the high absorption efficiency of the MPA in the near-infrared band is due to LSP resonance,and the high absorption efficiency of the MPA in the visible band is due to the PSP resonance. However,when VO2 is at high temperature,the high absorption efficiency of the MPA in the near-infrared band is caused by FP resonance. The research in this paper can provide a theoretical basis for design and fabrication of a high-performance,dynamic,adjustable MPA in the future.

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    Xiaowei JIANG, Sheng WANG, Hua WU. Metamaterial Absorber with Tunable Absorption Bandwidth Based on Vanadium Dioxide[J]. Acta Photonica Sinica, 2022, 51(1): 0151124
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