• Spectroscopy and Spectral Analysis
  • Vol. 29, Issue 11, 3141 (2009)
HUANG Ming-li*, LI Li-na, WANG Juan, and HAN Wen-xuan
Author Affiliations
  • [in Chinese]
  • show less
    DOI: Cite this Article
    HUANG Ming-li, LI Li-na, WANG Juan, HAN Wen-xuan. Application of ICP-MS to Species Determination of Pb, As and Cd in Hoggery Waste[J]. Spectroscopy and Spectral Analysis, 2009, 29(11): 3141 Copy Citation Text show less

    Abstract

    Distribution of heavy metal species in animal wastes needs to be monitored to control the heavy metal pollution during the utilization of wastes. Here, ICP-MS was applied to determine the speciation of Pb, As and Cd in the wastes from two hoggeries in the suburb of Beijing. The air-dried and finely ground samples were digested by HNO3-HClO4, or, sequentially extracted with BCR procedure before content determination of heavy metals. The total concentrations of Pb, As and Cd were 29.0, 28.2 and 0.288 mg·kg-1 dry weight (DW) in the fresh hoggery wastes respectively, and 19.7, 28.2 and 0.134 mg·kg-1 DW in the dry-cleaning waste, respectively. The concentrations of the three metals in both fresh and dry-cleaning wastes were all lower than the control standards for urban wastes for agricultural use promulgated by the national government, although As was close to the control value. Over 50% of Pb, As and Cd in the fresh waste were exchangeable/carbonate species, and less than 20% were organic/sulphide. However, species distributions of the heavy metals changed markedly after the process of dry-cleaning. The fraction of highly ecotoxic species (exchangeable/carbonate bound and Fe/Mn oxide bound) in the dry-cleaning waste decreases by 5%-25% for the three metals, indicating reduced risks of heavy metal pollutions when dry-cleaning wastes are applied to farmlands. This study contributes basic data for the resource utilization and ecological security assessment of hoggery wastes from Beijing.
    HUANG Ming-li, LI Li-na, WANG Juan, HAN Wen-xuan. Application of ICP-MS to Species Determination of Pb, As and Cd in Hoggery Waste[J]. Spectroscopy and Spectral Analysis, 2009, 29(11): 3141
    Download Citation