Celestial navigation technology has entered a new stage of development with the development of electronic technology and computer technology. Otherwise it has been widely used in satellite, space shuttle, long-range missiles and other spacecraft. Star centroid location for celestial navigation is the key technologies. Due to the strong sky background, near-infrared stellar images which are taken during the day have the low signal noise ratio. First, this paper adopts the method of information entropy to make analysis the stellar images energy distribution. And then we proposed a method for star target centroid located based on multi-step minimum energy difference. This method uses the linear superposition to narrow the centroid area, using the symmetry of the stellar energy distribution to obtain the centroid when the minimum difference appears. We test the modal on natural pictures to verify the accuracy. Experiments show that it has good effect to calculate the centroid with low SNR conditions.