There are some impurities such as aluminum dioxide adhering on the shock tube wall due to the ablating and heating of the aluminum diaphragm by high temperature gas. Under high temperature, the collision of AlO radicals with the gaseous molecules leads to transition of the electronic states and production of strong radiation, which disturb the analysis of radiation spectrum of heated gases in shock tube. In the authors’ experiments, the air in the test section with adhering aluminum dioxide was heated to some 4 000-7 000 K, the spectrum of AlO radical was obvious in the range of 460-530 nm, which corresponds to B 2Σ＋-X 2Σ＋(T00=20 689 cm-1 band. There were several band heads for this band, the interval of neighbor heads was some 2 nm, and all the band heads were with the shortest wavelength. The characteristics of B 2Σ＋-X 2Σ＋ band were explored in experiment and by theory. In addition, the spectrum of C 2Πr-X 2Σ+(T00=33 047 cm-1) band was also investigated. The corresponding strength was lower than that of B 2Σ+-X 2Σ+ band, and the wavelength range of this band was some 270-335 nm where the radiation of A 2Σ+-X 2Π (T00=32 682 cm-1) band of OH radical also existed. This occurrence of the two bands in the same wavelength range is disadvantageous for the spectrum analysis.