At present, the Inconel690 nickel-based alloy and SUS304 stainless steel are widely used in nuclear power, aerospace, and petrochemical fields owing to their excellent performance in thermal strength, corrosion resistance, and specific strength. Compared with traditional welding methods, laser welding is characterized by higher energy density, smaller welding deformation, and a narrower heat-affected zone. Compared with laser welding, laser welding with filler wire achieves the purpose of changing the metal composition of weld seams and thereby improving the mechanical properties of the welded joints. Different materials have different laser absorptivity, linear expansion coefficients, specific heat capacity, thermal conductivity, and microstructure evolution during solidification. These factors further affect the performance of the welded joints of dissimilar materials. The current research on stainless steel and nickel-based super-alloys mainly focuses on the mechanical properties of the welded joints under the influence of precipitates. In this study, laser welding and laser welding with filler wire are carried out under different heat inputs, and mechanical properties are investigated.
The thickness of the SUS304 and Inconel690 used in this experiment is 4.5 mm. Inconel ERNiCrFe-7A is used as the filler wire. The welding equipment used in this study is a 10 kW TRUMPF lasers TruDisk 10002. In addition, 99.99% pure argon gas is used as the shielding gas with a gas flow rate of 25 L/min. After welding, the ZEISS Axio Observer A1m metallurgical microscope is used to observe the surface morphology, and energy dispersive spectroscopy is employed to test the precipitates in the weld seams. The CMT4303 electronic universal testing machine is applied to test the tensile strength of the welded joints. The HVS-30 Vickers hardness tester is utilized to test the microhardness of the welded joints.
The cross-sections of the welded joints are in the typical goblet shape with no crack defects. In the weld zone S2 (1.5 kJ/cm), many white particles are observed near the grain boundary, and they can be further confirmed as a titanium-containing phase. After the ERNiCrFe-7A filler wire is added, an irregularly shaped white precipitated phase is observed in the weld seam, and it can be determined as a chromium-rich phase. The X-ray diffraction (XRD) results suggest that this chromium-rich phase is Cr0.19Fe0.7Ni0.11 phase. The tensile strength of S2 (1.5 kJ/cm) is 9.7% higher than that of S1 (2.6 kJ/cm). After the filler wire is added, the tensile strength of S3 (1.5 kJ/cm) is 683 MPa, which is 16.2% higher than that of S1 (2.6 kJ/cm). Owing to the decrease in heat input, the grain size in the weld seam becomes smaller, which improves the plastic toughness and average hardness of the weld seam. When the heat input are 2.6 kJ/cm and 1.5 kJ/cm, the average hardness of the weld seam are 176.8 HV and 190.4 HV, respectively. After the filler wire is added, the average hardness of the weld seam in weld zone S1 (2.6 kJ/cm) is 216.7 HV.
In this study, laser butt welding of Inconel690 nickel-based alloy and SUS304 stainless steel is carried out. The influences of heat input and filler metal on the microstructure and mechanical properties of joints are studied. The results indicate that the cross-section of the weld seam is in the classical goblet shape after laser welding. The weld width of S1 (2.6 kJ/cm) is larger than that of S2 (1.5 kJ/cm). As the heat input increases, the grain size in the weld seam becomes larger. A titanium-containing phase is diffusively distributed in the weld seams of all welded joints. After the ERNiCrFe-7A filler wire is added, a chromium-rich phase appears, and it is speculated to be Cr0.19Fe0.7Ni0.11 phase according to the XRD results. The grain size of S2 (1.5 kJ/cm) is 40% smaller than that of S1 (2.6 kJ/cm), and the mechanical properties of the joints are improved.
In this paper, a novel, highly-strained InGaAs/GaAs self-fit well-cluster composite (WCC) quantum structure was investigated. The WCC structure differs from the conventional InGaAs/GaAs quantum-well structure, which exhibits considerable potential for numerous laser applications. Presently, the conventional quantum well exhibits a quasirectangle well structure, wherein each well consists of a fixed amount of indium and a single strain type in the material system. The WCC structure with variable indium content and thickness in an InxGa1-xAs/GaAs system can yield remarkable results, thereby facilitating the development of new laser types. This structure is associated with the indium-rich cluster (IRC) effect, wherein the IRCs were typically regarded as defects to be avoided for the conventional InGaAs quantum-well structure; hence, its special optical characteristics remain neglected. The migration of the indium atoms to the WCC structure would reduce the indium content in the corresponding InGaAs regions, consequently generating normal and indium-deficient InxGa1-xAs regions with hybrid strain types in the InGaAs material and aid in the production of special polarized spectra with dual peaks. Therefore, it is crucial to reveal the underlying corresponding luminescence mechanism between dual peaks in different polarized spectra and multiple InxGa1-xAs materials. This work offers new avenues for the development of new types of devices.
First, the InGaAs-based WCC quantum structure was developed via metal-organic chemical vapor-phase deposition. To generate the IRC effect by sufficient strain accumulation, the In0.17Ga0.83As/GaAs/GaAsP0.08 material system was designed as a periodic gain structure (Fig.1). The thickness of the In0.17Ga0.83As layer was designed to be 10 nm, because an InGaAs layer thinner than 10 nm is insufficient to obtain the IRC effect. Second, the luminescence mechanism of the WCC structure was studied by coating the WCC sample at a transmittance of T=99.99% at the dual facets to avoid the end reflection. Third, the polarized photoluminescence (PL) spectra in transverse electric (TE) and transverse magnetic (TM) modes were measured using a linear polarizer under varying carrier densities (N) in the range of
The TE- and TM-polarized PL spectra (Fig.2) reveal the special bimodal features, and they are marked using letters A and B, and C and D, which correspond to 1.27 eV and 1.33 eV and 1.35 eV and 1.31 eV, respectively. GaAs, In0.17Ga0.83As, and In0.12Ga0.88As yield lattice constant values of 5.65325, 5.72215, and 5.7019 ?, respectively. Accordingly, the In0.17Ga0.83As layer is subject to compressive strain such that the HH1 subband lies above the LH1 subband. Meanwhile, tensile strain is noted in the In0.12Ga0.88As layer such that the HH1 subband falls below the LH1 subband. According to the transition matrix element theory, the main peaks, which are marked by A and C in both TE and TM spectral curves (Fig.2), are attributed to the compressively-strained In0.17Ga0.83As layer; the corresponding TE photon energy is less than the TM photon energy. Meanwhile, the subpeaks marked by B and D (Fig.2) are attributed to the tensile-strained In0.12Ga0.88As region; the corresponding TE photon energy exceeds the TM photon energy. Moreover, the characteristics of the hybrid energy band of the InGaAs self-fit WCC quantum structure are obtained (Fig.3). For the compressively-strained In0.17Ga0.83As layer, the energy intervals from C1 to HH1 and LH1 bands are 1.27 eV and 1.35 eV, which correspond to the photon energy at peaks A and C, respectively. In the case of the tensile-strained In0.12Ga0.88As material, the energy intervals from C1 to HH1 and LH1 bands are 1.33 eV and 1.31 eV, which correspond to the photon energy at peaks B and D, respectively.
In this paper, a novel, highly-strained InGaAs/GaAs self-fit WCC quantum structure is investigated based on the IRC effect. The measured spectra in TE and TM polarizations reveal special features with dual peaks, which are attributed to the combination of different emissions produced by the normal and indium-deficient InGaAs active regions. According to the transition matrix element theory, the corresponding luminescence mechanism between the dual peaks in polarized spectra and InGaAs material with different indium content is revealed. Furthermore, the band characteristics associated with the conduction subband C1 and valence subbands of heavy holes HH1 and light holes LH1 are determined to reveal the underlying luminescence mechanism. The special WCC structure demonstrates a hybrid strain distribution, which indicates the simultaneous existence of compressive and tensile strains. The results of this study can greatly enhance the performance of InGaAs-based WCC-tunable lasers.