• PhotoniX
  • Vol. 1, Issue 1, 17 (2020)
Yanming Zhu, Wei Zheng*, Weiliang Wang, Siqi Zhu, Linxuan Li, Lu Cheng, Mingge Jin, Ying Ding, and Feng Huang
Author Affiliations
  • State Key Laboratory of Optoelectronic Materials and Technologies, School of Materials, Sun Yat-sen University, Guangzhou, 510275 Guangdong, China
  • show less
    DOI: 10.1186/s43074-020-00017-7 Cite this Article
    Yanming Zhu, Wei Zheng, Weiliang Wang, Siqi Zhu, Linxuan Li, Lu Cheng, Mingge Jin, Ying Ding, Feng Huang. Raman tensor of layered black phosphorus[J]. PhotoniX, 2020, 1(1): 17 Copy Citation Text show less

    Abstract

    Black phosphorus has a strong Raman anisotropy on the basal and cross planes due to its orthorhombic crystal structure. However, almost all the studies on black phosphorus’ anisotropy focus on basal plane with the cross plane neglected. Here, we performed a systematic angle-resolved polarized Raman scattering on both the basal and cross planes of black phosphorus and obtained its integral Raman tensors. It is discovered that when the polarization direction of excitation light is along different crystal axes, the Raman intensity ratio (Ixx : Iyy: Izz) of $$ {A}_g^1 $$ mode is 256:1:5. Besides, via calculation, it is confirmed that the strong Raman anisotropy mainly comes from different differential polarizability alone different directions. This phenomenon is also observed when it comes to the $$ {A}_g^2 $$ mode.
    Yanming Zhu, Wei Zheng, Weiliang Wang, Siqi Zhu, Linxuan Li, Lu Cheng, Mingge Jin, Ying Ding, Feng Huang. Raman tensor of layered black phosphorus[J]. PhotoniX, 2020, 1(1): 17
    Download Citation